Yes, transaction limits also apply. You can only request a portion of your gross wages* (after taxes). The maximum amount per transaction is $200, and the minimum amount per transaction is $25. The maximum withdrawal amount per week is $1,500 (per active pay period).
You are only able to pull funds from the current pay period (Sunday 12:00am - Saturday 11:59pm).
Learn more by reading, "How much money can I withdraw using PayOnDemand or the PayCard?"
*A portion of your gross wages is withheld for tax purposes.